Hetero-ansa-metallocenes: I. Synthesis of the novel [1]-borylidene-bridged ansa-zirconocene dichloride

DOI: 10.1016/S0022-328X(96)06285-7

Source and publish data:

Journal of Organometallic Chemistry p. 287 - 289 (1996)

Update date:2022-08-04

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Authors:

Rufanov, Konstantin A.

Kotov, Vasiliy V.

Kazennova, Nadezhda B.

Lemenovskii, Dmitry A.

Avtomonov, Evgeniy V.

Lorberth, Joerg

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Article abstract of DOI:10.1016/S0022-328X(96)06285-7

The first ansa-[1]-zirconocene dichloride with the boron bridge atom, [(μ-PhB)(η⁵-C₅H₄)₂]ZrCl₂ (5) is synthesised via subsequent transmetallation of C₅H₄(SnMe₃)_2<

Full text of DOI:10.1016/S0022-328X(96)06285-7

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Product name:(C₆H₅)B(C₅H₄)2ZrCl₂

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