meso,meso-Linked porphyrin arrays

DOI: 10.1002/anie.199701351

Source and publish data:

Angewandte Chemie - International Edition in English p. 135 - 137 (1997)

Update date:2022-07-29

Topics:

Authors:

Osuka Osuka

Shimidzu

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Article abstract of DOI:10.1002/anie.199701351

The perpendicular arrangement of porphyrin units in dimer 1 is reflected in a large excitonic coupling that leads to splitting of the Soret bands and only modest spectral changes in the Q-bands. Compound 1 and the analogous trimer and tetramer are prepared by oxidative coupling of the corresponding 5,15-diaryl-porphyrin and are the first examples of compounds having direct meso,meso-linked porphyrin chromophores, Ar = 3.5-tBu₂C₆H₃.

Full text of DOI:10.1002/anie.199701351

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