Synthesis and reactivity of S-sulfiliminothiazynes

DOI: 10.1246/cl.1997.153

Source and publish data:

Chemistry Letters p. 153 - 154 (1997)

Update date:2022-07-30

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Authors:

Ohkubo, Masanori

Fujii, Takayoshi

Ono, Shin

Morita, Hiroyuki

Yoshimura, Toshiaki

Horn, Ernst

Sato, Soichi

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Article abstract of DOI:10.1246/cl.1997.153

Reaction of S,S-diphenyl-S-fluorothiazyne with N-unsubstituted S,S-diphenylsulfilimine afforded the corresponding S-sulfiliminothiazyne. Measurement of the pKa value of S-sulfiliminothiazyne and its reactivity were examined. The molecular structure of the sulfonediiminosulfonium salt was determined by the X-ray crystallographic analysis.

Full text of DOI:10.1246/cl.1997.153

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