Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation

DOI: 10.1021/jacs.7b07808

Source and publish data:

Journal of the American Chemical Society p. 13276 - 13279 (2017)

Update date:2022-08-03

Topics:

Authors:

Wijeratne, Gayan B.

Hematian, Shabnam

Siegler, Maxime A.

Karlin, Kenneth D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jacs.7b07808

A copper complex, [Cu^I(tmpa)(MeCN)]⁺, effectively reductively couples NO_(g) at RT in methanol (MeOH), giving a structurally characterized hyponitrito-dicopper(II) adduct. Hydrogen-bonding from MeOH is critical for the hyponitrite complex formation and stabilization. This complex exhibits the reverse redox process in aprotic solvents, giving Cu^I + NO_(g), leading to Cu^I-mediated NO_(g)-disproportionation. The relationship of this chemistry to biological iron and/or copper mediated NO_(g) reductive coupling to give N₂O_(g) is discussed.

Full text of DOI:10.1021/jacs.7b07808

Products guided by the article

Product name:[copper(I)(tris(2-pyridylmethyl)amine)]⁽¹⁺⁾

Cas No:188637-84-5

R&D Labs maybe for 188637-84-5

waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China

Relevant to this article

Benzhydrylamine: An effective aminating agent for the synthesis of primary amines

Doi:10.3184/174751918X15232662638058
(2018)
Synthesis of 2-Aryl-10b,10c-dimethyl-10b,10c-dihydropyrenes and a Study of Their Conjugation Behavior: Linear Relationship between the Degree of Conjugation and the Electronic Nature of Substituents

Doi:10.1021/jo962337i
(1997)
Doi:10.1021/jo01106a020
(1958)
Studies toward lipid A: Synthesis of differentially protected disaccharide fragments

Doi:10.1021/jo961668s
(1997)
Doi:10.1021/jo01256a063
(1969)
Spirocyclic nonpeptide glycoprotein IIb-IIIa antagonists. Part 1: Design of potent and specific 3,9-diazaspiro[5.5]undecanes

Doi:10.1016/S0960-894X(01)00215-3
(2001)

Article Doi