Journal of Organometallic Chemistry p. 59 - 63 (1997)
Update date:2022-08-04
Topics:
Mentes, Ayfer
Kemmitt, Raymond D.W.
Fawcett, John
Russell, David R.
Triphenylantimony reacts with [PdX2cod] (X = Cl or Br; cod = cyclo-octa-1,5-diene) in refluxing dichloromethane to give the palladium phenyl complexes trans-[PdXPh(SbPh3)2]. Treatment of palladium(II) chloride with triphenylantimony in refluxing acetone-diethyl ether solution also gives trans-[PdClPh(SbPh3)2], but reaction of palladium(II) bromide with triphenylantimony affords cis-[PdBr2(SbPh3)2]. A small amount of trans-[PdClPh(SbPh3)2] is present in samples of cis-[PdCl2(SbPh3)2] prepared from the reaction of Na2PdCl4 with triphenylantimony in aqueous acetone-diethyl ether. The single crystal X-ray structures of trans[PdXPh(SbPh3)2] (X = Cl or Br) are described.
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