Tetrahedron p. 6337 - 6350 (1997)
Update date:2022-08-04
Topics:
Kawasaki, Ken-Ichi
Katsuki, Tsutomu
Optically active copper(II)-tris(oxazoline) complex that was synthesized as a model compound of the active site of non-heme oxygenase, was found to catalyze allylic oxidation of cycloalkenes to give the corresponding 2-cycloalkenyl benzoates with moderate to excellent enantioselectivity (up to 93% ee) under die Kharash-Sosnovsky reaction conditions.
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