Metal cyanonitrosyl complexes: Synthesis, magnetic, thermal and spectral studies of some novel mixed-ligand cyanonitrosyl {MnNO}6 complexes of manganese(I) with potentially mono- and bidentate aniline derivatives

Article abstract of DOI:10.1080/00945719708000216

Novel mixed-ligand cyanonitrosyl {MnNO}⁶ complexes of manganese(I), formed by the interaction of pentacyanonitrosyl-manganate(I) anion, [Mn(NO)(CN)₅]^3-, with potentially bidentate aniline derivatives, viz., o-phenylenediamine (o-PDA, I), m-phenylenediamine (m-PDA, II), and potentially monodentate aniline derivatives, o-anisidine (o-ANS, III), m-anisidine (m-ANS, IV), p-anisidine (p-ANS, V), o-phenetidine (o-PD, VI) and m-phenetidine (m-PU, VII), are described. The resulting mixed-ligand complexes, which have been characterized by analytical data, electrical conductances, magnetic measurements, electronic spectra, thermogravimetric analyses and infrared spectral studies, have the compositions [Mn(NO)(CN)₂(o-PDA)(H₂O)], [Mn(NO)(CH)₂(m-PDA)-(H₂O)₂] or [Mn(NO)(CN)₂(L)₂(H₂O)] (where L = III, IV, V, VI or VII). Suitable octahedral structures have been proposed for the complexes. Manganese(I) has a low-spin {MnNO}₆ electron configuration in these complexes.

Full text of DOI:10.1080/00945719708000216

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Synthesis and Reactivity in
Inorganic and Metal-Organic
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Metal Cyanonitrosyl
Complexes: Synthesis,
Magnetic, Thermal and Spectral
Studies of Some Novel Mixed-
Ligand Cyanonitrosyl {MnNO}
Complexes of Manganese(I)
with Potentially Mono- and
Bidentate Aniline Derivatives
R. C. Maurya a , H. Singh a , J. Dubey a & G. P.
Shukla a
a Coordination Chemistry Laboratory, Department
of P. G. Studies and Research in Chemistry , R. D.
University , Jabalpur, 482 001, India
Published online: 20 Aug 2006.
To cite this article: R. C. Maurya , H. Singh , J. Dubey & G. P. Shukla (1997) Metal
Cyanonitrosyl Complexes: Synthesis, Magnetic, Thermal and Spectral Studies of Some
Novel Mixed-Ligand Cyanonitrosyl {MnNO} Complexes of Manganese(I) with Potentially
Mono- and Bidentate Aniline Derivatives, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 27:5, 647-660, DOI: 10.1080/00945719708000216
To link to this article: http://dx.doi.org/10.1080/00945719708000216
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