A new method for synthesizing dialkoxytin(II) and mono and diaryloxytin(II) compounds

Article abstract of DOI:10.1080/00945719708000227

The reactions of bis(β-diketonato)tin(II), such as bis(2, 4-pentanedionato)tin(II), Sn(acac)₂, bis(1-ethoxy-1, 3-butanedionato)tin(II), Sn(etac)₂, and bis(1-methoxy-1, 3-butanedionato)-tin(II), Sn(mtac)₂, with sodium alkoxide (NaOR, R = CH₃, C₂H₅) in alcohol/benzene at room temperature have been found to give the corresponding dialkoxytin(II) compounds. Sn(acac)₂ reacted also with o-substituted phenols [O-X-C₆H₄OH; X = CH₃CO, CH₃OC(O), CH₃O, Cl, (CH³)₃C] in a molar ratio of 1:2 at 90°C to afford the corresponding monosubstituted tin(II) compound, [Sn(OC₆H₄-X)(acac)], but the reaction with C₆H₅OH produced only the diphenoxide, Sn(OC₆H₅)₂.

Full text of DOI:10.1080/00945719708000227

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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A New Method for Synthesizing
Dialkoxytin(II) and Mono and
Diaryloxytin(II) Compounds
Ikuko Wakeshima a , Toshitaka Suzuki a , Akihiko
Takemoto a & Ichiro Kijima a
a Department of Industrial Chemistry, Faculty
of Engineering , Science University of Tokyo ,
Kagurazaka, Shinjuku-ku, Tokyo, 162, Japan
Published online: 20 Aug 2006.
To cite this article: Ikuko Wakeshima , Toshitaka Suzuki , Akihiko Takemoto &
Ichiro Kijima (1997) A New Method for Synthesizing Dialkoxytin(II) and Mono and
Diaryloxytin(II) Compounds, Synthesis and Reactivity in Inorganic and Metal-Organic
Chemistry, 27:5, 787-796, DOI: 10.1080/00945719708000227
To link to this article: http://dx.doi.org/10.1080/00945719708000227
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