Journal of Organometallic Chemistry p. 147 - 153 (1997)
Update date:2022-08-03
Topics:
Campi, Eva M.
Jackson, W. Roy
McCubbin, Quentin J.
Trnacek, Andrew E.
Reactions of several allyloxy-and allylamino-benzylamines and a benzamide with [Rh(CO)2Cl]2 give monodentate rhodium complexes which show no evidence of alkene coordination. Reaction of these and related compounds with HRh(CO)(PPh3)3 give products arising from double bond isomerisation followed by cyclisation or liberation of propene. The results are compared with rhodium-catalysed reactions of these substrates with H2/CO.
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(1997)
