Asymmetric induction reactions. VII. Palladium-catalyzed asymmetric α- allylations of carbonyl compounds using chiral sulfonamides as chiral ligands

DOI: 10.1248/cpb.45.769

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Chemical and Pharmaceutical Bulletin p. 769 - 777 (1997)

Update date:2022-08-05

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Authors:

Hiroi, Kunio

Hidaka, Akira

Sezaki, Rie

Imamura, Yumiko

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Article abstract of DOI:10.1248/cpb.45.769

Palladium-catalyzed asymmetric α-allylations of carbonyl compounds were studied using various kinds of chiral sulfonamides derived from optically active α-amino acids as chiral ligands. Participation of the sulfonamide functionality in the palladium catalysis is discussed.

Full text of DOI:10.1248/cpb.45.769

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