Chemical and Pharmaceutical Bulletin p. 962 - 965 (1997)
Update date:2022-08-03
Topics:
Maeda, Mikiko
Okazaki, Fumiaki
Murayama, Mayumi
Tachibana, Yohko
Aoyagi, Yutaka
Ohta, Akihiro
A short synthetic route to (-)-bulgecinine (1), the amino acid moiety of bulgecins, was established by using 1,3-dipolar cycloaddition of N-benzyl- α-methoxycarbonylmethanimine N-oxide (6) to a chiral allylic alcohol (5) with moderate threo selectivity as the key reaction.
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