Total synthesis of (-)-bulgecinine

DOI: 10.1248/cpb.45.962

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 962 - 965 (1997)

Update date:2022-08-03

Topics:

Authors:

Maeda, Mikiko

Okazaki, Fumiaki

Murayama, Mayumi

Tachibana, Yohko

Aoyagi, Yutaka

Ohta, Akihiro

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Article abstract of DOI:10.1248/cpb.45.962

A short synthetic route to (-)-bulgecinine (1), the amino acid moiety of bulgecins, was established by using 1,3-dipolar cycloaddition of N-benzyl- α-methoxycarbonylmethanimine N-oxide (6) to a chiral allylic alcohol (5) with moderate threo selectivity as the key reaction.

Full text of DOI:10.1248/cpb.45.962

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