Tetrahedron Letters p. 5249 - 5252 (1997)
Update date:2022-08-03
Topics:
Evans, P. Andrew
Roseman, Jamie D.
The intramolecular acyl radical cyclization of the acyl selenide 8, using a Z-vinylogous sulfonate to control rotamer population, affords the cis-2,6-disubstituted tetrahydropyran-4-one 9, applicable to the potent antitumor agent mucocin 1 in 81% yield.
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