A Novel Sm(II)-Induced Route to Highly Substituted Benzannulated Cyclooctanol Derivatives

DOI: 10.1055/s-1997-934

Source and publish data:

Synlett p. 995 - 997 (1997)

Update date:2022-08-02

Topics:

Authors:

Khan, Faiz Ahmed

Czerwonka, Regina

Zimmer, Reinhold

Reissig, Hans-Ulrich

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Article abstract of DOI:10.1055/s-1997-934

Siloxycyclopropane derivatives 3 with a suitable styrene side chain can effectively be ring opened to precursors 2 which undergo reductive ring closure with SmI₂ to furnish benzannulated cyclooctanols 1 or lactones 7 derived thereof. Tricyclic

Full text of DOI:10.1055/s-1997-934

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