Synlett p. 911 - 912 (1997)
Update date:2022-08-03
Topics:
Yoda, Hidemi
Nakajima, Tomohito
Takabe, Kunihiko
An efficient and novel process is described for the asymmetric synthesis of (6S,7R,8R,8aR)-6,7,8-trihydroxyindolizidine alkaloid, 1-deoxycastanospermine in 22% overall yield based on the C2-imide featuring the completely stereoselective reduction of an α-hydroxypyrrolidine intermediate elaborated through asymmetric deoxygenation of a quaternary α-hydroxylactam.
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Doi:10.1007/s11172-018-2135-2
(2018)Doi:10.1021/jo9711089
(1997)Doi:10.1016/S0040-4020(97)00894-6
(1997)Doi:10.1021/jo970666k
(1997)Doi:10.1016/S0008-6215(97)00156-0
(1997)Doi:10.1055/s-1997-1522
(1997)
