Pericyclic reactions in nature: Synthesis and Cope rearrangement of thermolabile bis-alkenylcyclopropanes from female gametes of marine brown algae (Phaeophyceae)

DOI: 10.1016/S0040-4020(97)00886-7

Source and publish data:

Tetrahedron p. 13681 - 13694 (1997)

Update date:2022-07-29

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Authors:

Pohnert, Georg

Boland, Wilhelm

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Article abstract of DOI:10.1016/S0040-4020(97)00886-7

The biosyntheses of the 6-substituted cyclohepta-1,4-dienes dictyotene (1), ectocarpene (2), desmarestene (3), vinylcycloheptadiene (4) and lamoxirene (5) involve a spontaneous Cope rearrangement of thermolabile bis-alkenylcyclopropane precursors like 16,

Full text of DOI:10.1016/S0040-4020(97)00886-7

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