Asymmetric total syntheses of hydroxylated piperidine alkaloids via the intramolecular reaction of γ-aminoallylstannane with aldehyde

Article abstract of DOI:10.1016/S0957-4166(97)00563-6

Asymmetric total syntheses of (+)-desoxoprosopinine and (-)- desoxoprosophylline were accomplished, using L-glutamic acid as the chiral source, in which the intramolecular reaction of a γ-aminoallylstannane with an aldehyde was used as a key step.