Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) 6[Zn(CH2Ph)3]2

DOI: 10.1016/S0022-328X(97)00050-8

Source and publish data:

Journal of Organometallic Chemistry p. 181 - 185 (1997)

Update date:2022-08-03

Topics:

Authors:

Rijnberg, Evelien

Jastrzebski, Johann T.B.H.

Boersma, Jaap

Kooijman, Huub

Spek, Anthony L.

Van Koten, Gerard

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Article abstract of DOI:10.1016/S0022-328X(97)00050-8

The addition of Mg(CH₂Ph)₂(thf)₂ to a thf solution of Zn(CH₂Ph)₂ yields the zincate complex Mg(thf)₆[Zn(CH₂Ph)₃]₂ (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cleaved by tmeda into a 1:2 mixture of Mg(CH₂Ph)₂(tmeda) and Zn(CH₂Ph)₂(tmeda).

Full text of DOI:10.1016/S0022-328X(97)00050-8

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