Angewandte Chemie - International Edition in English p. 2004 - 2006 (1997)
Update date:2022-07-30
Topics:
Huang
Streib
Eisenstein
Caulton
A nonplanar arrangement of four ligands is intrinsic to the title compound in solution and in the crystal. There is no interaction between the Ru center and the counterion [3,5-(CF3)2C6H3]4B-. Density functional theory calculations of the model complex [Ru(Ph)(CO)(PH3)2]+ provided the structure shown on the right, which shows no ortho-CH···Ru interaction.
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(1997)
