Tetrahedron p. 15011 - 15028 (1997)
Update date:2022-08-03
Topics:
Bertani, Barbara
Di Fabio, Romano
Ghiron, Chiara
Perboni, Alcide
Rossi, Tino
Thomas, Russell J.
Zarantonello, Paola
The synthesis of 4-aminocarbonylmethoxy trinems was accomplished through Lewis acid catalysed opening of an epoxide intermediate with allyl glycolate, followed by deallylation, activation of the free acid via the 2-pyridyl thiolester and reaction with a series of trimethylsilylamines. An alternative route involving a rhodium-catalysed diazoacetate insertion was also successfully exploited.
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(2019)Doi:10.1039/b805767b
(2008)Doi:10.1016/S0040-4020(97)10050-3
(1997)Doi:10.1016/S0040-4039(97)10282-9
(1997)Doi:10.1021/om970504e
(1997)Doi:10.1021/ac0204193
(2003)
