Oxidation of Rh(I)(olefin) fragments to 2-Rhoda(III)oxetanes

DOI: 10.1002/anie.199720641

Source and publish data:

Angewandte Chemie - International Edition in English p. 2064 - 2067 (1997)

Update date:2022-08-04

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Authors:

De Bruin

Boerakker

Donners Donners

Christiaans

Schlebos

De Gelder

Smits Smits

Spek Spek

Gal Gal

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Article abstract of DOI:10.1002/anie.199720641

Stable unsubstituted 1,2-oxarhodacyclobutanes (2-rhodaoxetanes) are obtained upon oxidation of [Rh(I)(ethene)'N₄']⁺ complexes [Eq.(a)]. Similar oxidation of [Rh(I)(cod)'N₃']⁺ complexes results in oxarhodatetracl

Full text of DOI:10.1002/anie.199720641

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