Asymmetric approaches to 1,2-disubstituted mitosenes based on the intramolecular cyclization of diazoesters

DOI: 10.1016/S0040-4020(97)01033-8

Source and publish data:

Tetrahedron p. 16521 - 16532 (1997)

Update date:2022-08-03

Topics:

Authors:

Lee, Sangku

Lim, Hee-Jong

Cha, Kobpurn Lulu

Sulikowski, Gary A.

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Article abstract of DOI:10.1016/S0040-4020(97)01033-8

A strategy for the asymmetric synthesis of 1,2-disubstituted mitosenes is described. The key reaction is the decomposition of a meso diazoester in the presence of chiral copper(I) catalysts. Cyclization of diazoesters derived from (1R, 2S, 5R)-menthol and

Full text of DOI:10.1016/S0040-4020(97)01033-8

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