Journal of the American Chemical Society p. 8674 - 8680 (1998)
Update date:2022-08-03
Topics: Retrosynthetic analysis Purification and characterization Final steps Assembly Fragmentation Synthesis of Intermediates
Nicolaou
Ohshima
Hosokawa
Van Delft
Vourloumis
Xu
Pfefferkorn
Kim
The total synthesis of the cytotoxic marine natural products eleutherobin (1) and eleuthosides A (2) and B (3) is described. The strategy involves glycosidation of the (+)-carvone-derived intermediate 7 with the arabinose-derived trichloroacetimidate 9 fo
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