Synlett p. 1263 - 1264 (1997)
Update date:2022-07-29
Topics: Ring-Closing Metathesis Experimental approach Carbohydrate Derivatives
Leeuwenburgh, Michiel A.
Overkleeft, Herman S.
Van Der Marel, Gijsbert A.
Van Boom, Jacques H.
A novel synthesis of both cis- and trans-fused pyranopyran systems, based on ring-closing metathesis of glycal derived dienes, is described. Isomerisation of the resulting allylic double bond provides a new cyclic enol ether, thus opening the way to an iterative synthesis of cis-(trans-)fused cyclic polyethers.
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