Tetrahedron p. 17669 - 17690 (1997)
Update date:2022-08-03
Topics:
Kempin, Uwe
Hennig, Lothar
Knoll, Dietmar
Welzel, Peter
Mueller, Dietrich
Markus, Astrid
Van Heijenoort, Jean
Moenomycin A (18) on reaction with the diazonium salt derived from bifunctional (protected) 15 yields the coupling product 19 which on reduction is converted into the moenomycin thiol derivative 21. Thiol 21 has been used to prepare selectively moenomycin dansyl and biotin adducts 26 and 28, respectively. This work was performed with the aim to use moenomycin as a tool for studies of the transglycosylation step in peptidoglycan biosynthesis.
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