C-glycosides: A stereoselective synthesis of α-C-galactosamines with a glycosyl dianion

DOI: 10.1016/S0040-4039(97)10567-6

Source and publish data:

Tetrahedron Letters p. 255 - 256 (1998)

Update date:2022-08-03

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Authors:

Burkhart, Fred

Kessler, Horst

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Article abstract of DOI:10.1016/S0040-4039(97)10567-6

α-C-glycosides of the galactosamine can be obtained from the configurationally stable α-glycosyl dianion which can be prepared by reductive lithiation of the chloride. Different electrophiles react selectively at the anomeric center.

Full text of DOI:10.1016/S0040-4039(97)10567-6

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