Tetrahedron Letters p. 9755 - 9758 (1994)
Update date:2022-09-26
Topics:
Bush, Edward J.
Jones, David W.
Thornton-Pett, Mark
Thermolysis of 4(X=H) gives 6a and 6b(X=H) in a ratio of 1:4 whereas 4 (X=SO2Ph) gives more of trans-ring junction product 6a(X=SO2Ph) suitable for the synthesis of pisiferol [ratio 6a: 6b(X=S)2Ph) = 1.5:1].
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