Synthesis of pisiferol revisited; control of stereochemistry in an intramolecular Diels-Alder reaction

DOI: 10.1016/0040-4039(94)88378-5

Source and publish data:

Tetrahedron Letters p. 9755 - 9758 (1994)

Update date:2022-09-26

Topics:

Authors:

Bush, Edward J.

Jones, David W.

Thornton-Pett, Mark

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)88378-5

Thermolysis of 4(X=H) gives 6a and 6b(X=H) in a ratio of 1:4 whereas 4 (X=SO₂Ph) gives more of trans-ring junction product 6a(X=SO₂Ph) suitable for the synthesis of pisiferol [ratio 6a: 6b(X=S)₂Ph) = 1.5:1].

Full text of DOI:10.1016/0040-4039(94)88378-5

Products guided by the article

Product name:7-(6-Benzenesulfonyl-5-hydroxy-4,4-dimethyl-hexyl)-3-isopropyl-4-methoxy-bicyclo[4.2.0]octa-1,3,5-triene-7-carbonitrile

Cas No:202258-17-1

R&D Labs maybe for 202258-17-1

Jiaxing Anrui Material Technology Co., Ltd.

Contact:86-573-82651652 13305832579

Address:Room 407, Technology Building, 1369 Chennan Road, Jiaxing City, Zhejiang, China
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park

Relevant to this article

Synthesis and reactivity of new palladium alkyl complexes containing PMe₃ ligands: Insertion reactions and formation of bis( pyrazolyl) borate derivatives

Doi:10.1016/S0022-328X(97)00495-6
(1997)
Palladium-catalyzed c(sp²)-n bond cross-coupling with triaryl phosphates

Doi:10.1021/acs.joc.9b00703
(2019)
Electronic structure of light-induced lophyl radical derived from a novel hexaarylbiimidazole with π-conjugated chromophore

Doi:10.1039/b203814e
(2002)
Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis

Doi:10.1021/jo0259358
(2002)
4-Amino-5-vinyl-3(2H)-pyridazinones and analogues as potent antinociceptive agents: Synthesis, SARs, and preliminary studies on the mechanism of action

Doi:10.1016/j.bmc.2007.05.035
(2007)
Synthesis of new derivatives of 4-quinolinecarboxylic acid [3]

Doi:10.1023/A:1015363931038
(2002)

Article Doi