Synthetic studies and mechanistic observations in nickel-catalyzed polycyclizations

DOI: 10.1016/S0040-4020(97)10213-7

Source and publish data:

Tetrahedron p. 1131 - 1144 (1998)

Update date:2022-08-04

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Authors:

Montgomery, John

Seo, Jeongbeob

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Article abstract of DOI:10.1016/S0040-4020(97)10213-7

A series of polyunsaturated enones were investigated in Ni(COD)₂/organozinc-mediated cyclizations. One substrate class underwent an efficient [2+2+2] cycloaddition reaction to generate a tricyclic ring system from a linear precursor. A discussion of probable mechanisms is provided.

Full text of DOI:10.1016/S0040-4020(97)10213-7

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