Organic Letters p. 2816 - 2819 (2015)
Update date:2022-08-03
Topics:
Zhang, Zhenhua
Du, Haifeng
A highly enantioselective cis-hydrogenation of 2,3,4-trisubstituted quinolines has been realized for the first time using chiral borane catalysts generated in situ from chiral dienes. A variety of tetrahydroquinoline derivatives containing three contiguous stereogenic centers were obtained in 76-99% yields with 82-99% ee's.
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Doi:10.1021/acs.joc.6b00872
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