Samarium diiodide-promoted diiodomethylation of carbonyl compounds with iodoform. Synthetic applications of diiodoalcohols

DOI: 10.1016/S0040-4039(97)10777-8

Source and publish data:

Tetrahedron Letters p. 1409 - 1412 (1998)

Update date:2022-08-03

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Authors:

Concellon, Jose M.

Bernad, Pablo L.

Perez-Andres, Juan A.

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Article abstract of DOI:10.1016/S0040-4039(97)10777-8

A rapid and effective diiodomethylation of carbonyl compounds using SmI₂ and iodoform is described. Transformations of the obtained diiodoalcohols 2 into α-iodoaldehydes 5 and α-hydroxyacids 6 is also reported.

Full text of DOI:10.1016/S0040-4039(97)10777-8

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