Heterocycles p. 2327 - 2330 (1997)
Update date:2022-08-05
Topics:
Somei, Masanori
Yamada, Fumio
Izumi, Tomoyuki
Nakajou, Masahiro
1-Methoxy-3-(2-nitrovinyl)indole (4) functions as an electrophile and reacted with various nucleophiles regioselectively at the 2-position. Employing allyl alkoxides as nucleophiles, a novel synthetic method of pyrrolo[2,3-b]indoles has been elaborated. Utilizing the method, the synthesis of (±)-debromofIustramine B (10b) was achieved.
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