Strigol and sorgolactone synthetic studies use of Winferfeldt's template to control the C-2' configuration

DOI: 10.1016/S0040-4039(97)01228-8

Source and publish data:

Tetrahedron Letters p. 5489 - 5492 (1997)

Update date:2022-08-04

Topics:

Authors:

Roehrig, Susanne

Hennig, Lothar

Findeisen, Matthias

Welzel, Peter

Mueller, Dietrich

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Article abstract of DOI:10.1016/S0040-4039(97)01228-8

A route comprising (i) a cycloaddition reaction of citraconic anhydride with the Winterfeldt auxiliary, (ii) hydride reduction of the cycloadduct, (iii) a (formal) ether formation, and (iv) a cycloreversion reaction allows efficient stereocontrol at C-2' in the synthesis of strigol and its structural analogues.

Full text of DOI:10.1016/S0040-4039(97)01228-8

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