Diastereoselective Oxidative Coupling of Enolates of Chiral Carboxylic Acid Derivatives

DOI: 10.1016/0040-4039(95)00786-C

Source and publish data:

Tetrahedron Letters p. 4409 - 4412 (1995)

Update date:2022-07-29

Topics:

Authors:

Langer, Thomas

Illich, Michael

Helmchen, Guenter

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Article abstract of DOI:10.1016/0040-4039(95)00786-C

Enolates of chiral propionic acid amides were oxidatively dimerized with cupric salts or iodine with high simple as well as induced diastereselectivity of up to 99:1.Intramolecular coupling of chiral dienolates of 1,7-heptanediamides led to a 1,2-substituted cyclopentane and a derivative of 1,2,6,7-cyclodecane tetracarboxylic acid.

Full text of DOI:10.1016/0040-4039(95)00786-C

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