Stereoselective hetero-claisen rearrangement of camphor derived oxazoline-N-oxides

DOI: 10.1016/S0040-4039(98)00062-8

Source and publish data:

Tetrahedron Letters p. 2107 - 2110 (1998)

Update date:2022-08-04

Topics:

Authors:

Dalko, Peter I.

Langlois, Yves

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00062-8

Camphor derived oxazoline-N-oxides in the presence of various acylating agents afforded α-acyloxyoxazolines resulting from a diastereoselective [3,3] rearrangement. The configuration of the newly formed asymmetric center was established by chemical correlation. The observed diastereoselectivity accounts a concerted rather than a stepwise process.

Full text of DOI:10.1016/S0040-4039(98)00062-8

Products guided by the article

Product name:(1R,2S,6R,7S)-1,10,10-Trimethyl-4-phenethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]dec-4-ene 5-oxide

Cas No:206438-90-6

R&D Labs maybe for 206438-90-6

Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.

Contact:0086-0576-88551200,88886292 ,88880039

Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Sinoway International (Jiangsu) Co., Ltd.

Contact:+86-25-86630167

Address:17 Beijing Road (West), Nanjing, China

Relevant to this article

Regioselective synthesis and properties of 3-cyano-6-thienylpyridine-2(1H)-thiones

Doi:10.1007/BF02498968
(1998)
Convergent functional groups: Intramolecular acyl transfer through a 34- membered ring [5]

Doi:10.1021/ja9733806
(1998)
Dimethyltin(IV) bis(3,5-diphenylpyrazolate) as a synthetic reagent in the preparation of rare-earth pyrazolate complexes

Doi:10.1002/ejic.200800642
(2008)
The synthesis of biphenylglyoxime and bis(phenylglyoxime) and their complexes with Cu(II), Ni(II) and Co(II)

Doi:10.1080/00945719809349362
(1998)
Ancillary aryloxide ligands in ethylene polymerization catalyst precursors

Doi:10.1016/S0022-328X(99)00422-2
(1999)
Note on the protection of the carbon amide groups of glutamine in peptide synthesis through 2,4-dimethoxy-benzyl residues

Doi:10.1002/cber.19681011039
(1968)

Article Doi