Aldehyde-Promoted Addition of 2-(Trimethylsilyl)thiazole to α,α'-Dialkoxy Ketones: A New Way to Branched-Chain Monosaccharides

DOI: 10.1002/hlca.19980810510

Source and publish data:

Helvetica Chimica Acta p. 889 - 901 (1998)

Update date:2022-08-05

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Authors:

Carcano, Michela

Vasella, Andrea

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Article abstract of DOI:10.1002/hlca.19980810510

The reaction of 2-(trimethylsilyl)thiazole (2-TST) with several ketones was tested in the presence or absence of aldehydes. The keto aldehyde 5 (Scheme 2) was prepared from 1 via the hydroxy aldehyde 4 in 3 steps. It reacted with 2-TST to give, after desi

Full text of DOI:10.1002/hlca.19980810510

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