Aldehyde-Promoted Addition of 2-(Trimethylsilyl)thiazole to α,α'-Dialkoxy Ketones: A New Way to Branched-Chain Monosaccharides

DOI: 10.1002/hlca.19980810510

Source and publish data:

Helvetica Chimica Acta p. 889 - 901 (1998)

Update date:2022-08-05

Topics:

Authors:

Carcano, Michela

Vasella, Andrea

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19980810510

The reaction of 2-(trimethylsilyl)thiazole (2-TST) with several ketones was tested in the presence or absence of aldehydes. The keto aldehyde 5 (Scheme 2) was prepared from 1 via the hydroxy aldehyde 4 in 3 steps. It reacted with 2-TST to give, after desi

Full text of DOI:10.1002/hlca.19980810510

Products guided by the article

Product name:allyl (R)-2,3:(R)-4,6-di-O-benzylidene-α-D-glucopyranoside

Cas No:208039-61-6

R&D Labs maybe for 208039-61-6

Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Zhongshan Haihong Medicine Co., Ltd.

Contact:86-0760-86925778 （0）18824993998

Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Tractus Company Limited

Contact:+852-8198 2399

Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong

Relevant to this article

Titanium hydrocarbyl complexes with a linked cyclopentadienyl-alkoxide ancillary ligand; participation of the ligand in an unusual activation of a (trimethylsilyl)methyl group

Doi:10.1021/om970867e
(1998)
Synthesis of derivatives of NK109, 7-OH benzo[c]phenanthridine alkaloid, and evaluation of their cytotoxicities and reduction-resistant properties

Doi:10.1016/S0960-894X(00)00467-4
(2000)
Doi:10.1246/bcsj.41.2540
(1968)
First total syntheses of (Z)-15-methyl-10-hexadecenoic acid and the (Z)-13-methyl-8-tetradecenoic acid

Doi:10.1016/j.chemphyslip.2006.10.003
(2007)
Sequential and cascade olefin metathesis - Intramolecular heck reaction

Doi:10.1016/S0040-4039(98)00709-6
(1998)
Syn -selective catalytic asymmetric 1,4-addition of α-ketoanilides to nitroalkenes under dinuclear nickel catalysis

Doi:10.1021/ol101185p
(2010)

Article Doi