Tetrahedron Letters p. 3509 - 3512 (1998)
Update date:2022-07-30
Topics:
Ino, Akira
Hasegawa, Yasushi
Murabayashi, Akira
A total synthesis of the antimycoplasma antibiotic micacocidin (1) is described. Construction of sterically hindered thiazoline 12 was achieved by a phosphorus pentachloride-mediated cyclization reaction of S-protected aryloylcysteine 11, and compound 1 with desired chirality at C-10 was favorably obtain from diastereomeric mixture 30 through formation of the Zn complex 31.
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Doi:10.1016/S0957-4166(98)00106-2
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