Unexpected fragmentations of triphosphaferrocene-formation of supramolecular assemblies containing the (1,2,4-P3C2Mes2)- ligand

DOI: 10.1039/c5dt00303b

Source and publish data:

Dalton Transactions p. 6502 - 6509 (2015)

Update date:2022-07-29

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Authors:

Heindl, Claudia

Kuntz, Andrea

Peresypkina, Eugenia V.

Virovets, Alexander V.

Zabel, Manfred

Lüdeker, David

Brunklaus, Gunther

Scheer, Manfred

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Article abstract of DOI:10.1039/c5dt00303b

While reacting the sterically demanding triphosphaferrocene [CpFe(η⁵-P₃C₂Mes₂)] (1) with Cu(i) halides, the sandwich complex undergoes an unprecedented fragmentation into decamethylferrocene, FeX₂ (X

Full text of DOI:10.1039/c5dt00303b

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