Tetrahedron p. 7401 - 7416 (1998)
Update date:2022-08-03
Topics:
Vilsmaier, Elmar
Herweck, Thomas
Schummel, Monika
Tetzlaff, Claus
Dotzauer, Matthias
Bergstraesser, Uwe
3-endo-Amino-2,4-cyclotropane- and 3 -endo-amino-2,4- cyclogranatanecarbonitriles could be synthesized from the enamines of tropinone or pseudopelletierines by subsequent reactions with N- chlorosuccinimide and cyanide. Configuration and conformation of the tricyclic unit in the new compounds were determined by 1H NMR spectroscopy. The plyers-like shape of the diamine unit was confirmed by an X-ray structural analysis.
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(1998)
