Biochemically relevant complexes of copper: Synthesis, magnetic and spectral studies of some mixed-ligand chelates of bis(o-hydroxyacetophenonato)copper(II) with benzothiazole and related ligands

Article abstract of DOI:10.1080/00945719809349388

A series of novel mixed-ligand complexes of copper(II) of the compositions [Cu(o-haph)₂(L)₂], where o-haphH = o-hydroxy-acetophenone and L = benzothiazole, 2-methylbenzothiazole, 2-(2′-hydroxyphenyl)benzothiazole, 2-(2′-tolyl)benzothiazole or 2-(3′-tolyl)benzothiazole, and [Cu(o-haph)₂(AMBZT)], where AMBZT = 2-aminobenzothiazole, have been prepared by the interaction of [Cu(o-haph)₂] .H₂O with the ligands. The compounds so obtained were characterized by analytical data, molar conductances, magnetic measurements, electron paramagnetic resonance and infrared spectral studies. Suitable octahedral structures have been proposed for these complexes.

Full text of DOI:10.1080/00945719809349388

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Synthesis and Reactivity in
Inorganic and Metal-Organic
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Biochemically Relevant
Complexes of Copper:
Synthesis, Magnetic and
Spectral Studies of Some
Mixed-Ligand Chelates of Bis(O-
Hydroxyacetophenonato)Copper(II)
with Benzothiazole and
Related Ligands
R. C. Maurya a , S. Pillai a , T. Singh a , H. Singh a
B. Shukla a
&
a Coordination Chemistry Laboratory, Department
of P. G. Studies and Research in Chemistry, R. D.
University, Jabalpur, 482 001, India
Version of record first published: 14 Apr 2008.
To cite this article: R. C. Maurya, S. Pillai, T. Singh, H. Singh & B. Shukla (1998):
Biochemically Relevant Complexes of Copper: Synthesis, Magnetic and Spectral
Studies of Some Mixed-Ligand Chelates of Bis(O-Hydroxyacetophenonato)Copper(II)
with Benzothiazole and Related Ligands, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 28:7, 1053-1064
To link to this article: http://dx.doi.org/10.1080/00945719809349388
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