A bridged spiro[6.6]silatridecane via double 7-endo radical cyclisation

DOI: 10.1016/S0040-4020(98)00620-6

Source and publish data:

Tetrahedron p. 10699 - 10702 (1998)

Update date:2022-08-04

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Authors:

Teng, Zhu

Keese, Reinhart

Stoeckli-Evans, Helen

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Article abstract of DOI:10.1016/S0040-4020(98)00620-6

The double intramolecular radical induced reaction of 5 gives in a highly regioselective reaction via a 7-endo mode the tricyclic silaalkane 7 in 42% yield. In addition. The bicyclic trisilane 8 also formed by a 7-endo cyclisation, is obtained in 33% yiel

Full text of DOI:10.1016/S0040-4020(98)00620-6

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Product name:2,5-Bis-(chloromethyl-dimethyl-silanyl)-3,4-diphenyl-1,1-divinyl-1H-silole

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