Asymmetric intramolecular radical vinylation using enantiopure sulfoxides as temporary chiral auxiliaries

DOI: 10.1021/ja992818u

Source and publish data:

Journal of the American Chemical Society p. 11395 - 11401 (1999)

Update date:2022-07-30

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Authors:

Delouvrié, Bénédicte

Fensterbank, Louis

Lac?te, Emmanuel

Malacria, Max

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Article abstract of DOI:10.1021/ja992818u

A very diastereoselective addition-elimination sequence affords cyclopentane derivatives in high enantiomeric purities. The enantiopure sulfoxide unit serves as a very efficient temporary chiral auxiliary in this tandem reaction. Interestingly, the presen

Full text of DOI:10.1021/ja992818u

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