Journal of Molecular Structure p. 93 - 104 (1983)
Update date:2022-08-05
Topics:
Lewandowski, Wlodzimierz
The structure of lanthanide complexes with benzoic acid was investigated by IR and UV absorption spectra.To determine the effect of metal coordination on the aromatic system of benzoic acid, IR spectra of Ln(OBz)3 (Ln is a lanthanide except promethium; BzO is benzoic acid radical) were compared with ligand and sodium benzoate spectra.Also, changes in frequency and relative intensity of the ν(C-C)ar bands in the 1600-1400 cm-1 region, were analyzed in terms of the atomic number of lanthanides.It is shown that lanthanides disturb the aromatic system of the benzoate ligand less than sodium.This effect is discussed in terms of the bond formed.
Yangzhou Zhongbao Pharmaceutical Co.,Ltd
Contact:+86-514-88290838
Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Nanyang Tianhua pharmaceutical Co.,Ltd.
Contact:+8618639816203
Address:Longsheng Industrial Park
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd
Contact:+86 411 84674606
Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)
Contact:+86-21-54159691
Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Doi:10.1016/S0040-4039(00)70815-X
(1968)Doi:10.1021/jo990843c
(2000)Doi:10.1021/acschembio.0c00732
(2020)Doi:10.1016/j.tetlet.2019.151167
(2019)Doi:10.1021/jo701966h
(2008)Doi:10.1016/S0022-328X(98)00772-4
(1998)
