Journal of Molecular Structure p. 93 - 104 (1983)
Update date:2022-08-05
Topics:
Lewandowski, Wlodzimierz
The structure of lanthanide complexes with benzoic acid was investigated by IR and UV absorption spectra.To determine the effect of metal coordination on the aromatic system of benzoic acid, IR spectra of Ln(OBz)3 (Ln is a lanthanide except promethium; BzO is benzoic acid radical) were compared with ligand and sodium benzoate spectra.Also, changes in frequency and relative intensity of the ν(C-C)ar bands in the 1600-1400 cm-1 region, were analyzed in terms of the atomic number of lanthanides.It is shown that lanthanides disturb the aromatic system of the benzoate ligand less than sodium.This effect is discussed in terms of the bond formed.
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)
Contact:010-52876516
Address:tongzhoubeiyuan
Jiangsu Taihu New Materials Holding Co., Ltd
Contact:+86-519-86160108
Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
DACHANG OLEOCHEMICALS CO.,LTD.
Contact:0543-2875999
Address:Xingbo 10 Road,EDZ,Boxing Town,Shandong
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd
Contact:0573-82613601
Address:Chemical Park, Jiaxing, Zhejiang, China
Shandong Hongchuan Chemical Co., Ltd
Contact:+86-546-8339803
Address:417# Meiyuan Building, South 1 Road
Doi:10.1016/S0040-4039(00)70815-X
(1968)Doi:10.1021/jo990843c
(2000)Doi:10.1021/acschembio.0c00732
(2020)Doi:10.1016/j.tetlet.2019.151167
(2019)Doi:10.1021/jo701966h
(2008)Doi:10.1016/S0022-328X(98)00772-4
(1998)
