Tetrahedron Letters p. 6927 - 6930 (1998)
Update date:2022-08-04
Topics:
Xin, Teng
Okamoto, Sentaro
Sato, Fumie
Chiral allyltitaniums prepared from cyclic carbamate of optically active 4-aminoalk-1-en-3-ols and a Ti(O-i-Pr)4/2i-PrMgCl reagent react with aldehydes with good to excellent regio- and stereoselectivity to afford optically active 1.5-amino alcohols, from which optically active 2,6-cis- disubstituted piperidines are synthesized.
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