Synthesis, alkylation, crystal structure and molecular mechanics investigations of the (methylthio) acetyliron complex [(η5-C5H5)Fe(CO)(PPh3)COCH2SCH3]

DOI: 10.1016/0022-328X(96)06340-1

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 7 (1996)

Update date:2022-08-05

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Authors:

Wisniewski, Krzysztof

Pakulski, Zbigniew

Zamojski, Aleksander

Sheldrick, William S.

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Article abstract of DOI:10.1016/0022-328X(96)06340-1

The air stable (methylthio)acetyliron complex 4 was obtained by methylthiolation with dimethyldisulphide of the anion generated from acetyliron complex 1 with butyllithium. Alkylthiolation could not be achieved with a number of thiolating reagents 5-11. T

Full text of DOI:10.1016/0022-328X(96)06340-1

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