Reagent- and chelation-controlled diastereoselective aziridination of electron-rich alkenes by 3-acetoxyamino-2-(1-hydroxy-2,2-dimethylprop-1-yl)-quinazolin-4(3H)-one

DOI: 10.1039/cc9960001935

Source and publish data:

Chemical Communications p. 1935 - 1936 (1996)

Update date:2022-07-29

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Authors:

Atkinson, Robert S.

Gattrell, William T.

Ayscough, Andrew P.

Raynham, Tony M.

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Article abstract of DOI:10.1039/cc9960001935

In the presence of titanium(iv) tert-butoxide, the title 3-acetoxyaminoquinazolinone aziridinates styrene, butadiene and indene completely diastereoselectively; the absolute configuration of the styrene-derived aziridine 6a is proven by X-ray crystallogra

Full text of DOI:10.1039/cc9960001935

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