
Tetrahedron p. 12609 - 12622 (1998)
Update date:2022-08-02
Topics:
Chen, Hong-Chuan
Chou, Ta-Shue
Isoquinolino-3-sulfolene 7 has been prepared efficiently from 3,4- epoxysulfolene 8. Deprotonation-alkylation reactions proceed smoothly but with low regioselectivity to give substituted isoquinolino-3-sulfolenes. The pyrolysis of these fused 3-sulfolenes at various temperatures provides an easy entry to the corresponding isoquinolino-o-quinodimethanes.
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