ASYMMETRIC REDUCTION OF ACETOPHENONE WITH CHIRAL REAGENTS FROM LITHIUM TETRAHYDROALUMINATE AND CHIRAL 1,2-DIOL OR DIAMINE AS STUDIED BY ALUMINUM-27 NUCLEAR MAGNETIC RESONANCE

Article abstract of DOI:10.1246/cl.1984.749

Asymmetric reduction of acetophenone with chiral reagents from lithium tetrahydroaluminate and (1S,2S)-1,2-diphenylethanediol or (1S,2S)-N,N'-diethyl-1,2-diphenylethanediamine in the presence or absence of added ethanol is studied by aluminum-27 NMR spectroscopy.