Synthesis of enantiomerically pure 3-amino-1,2-diols by reductive amination of racemic 2,3-dialkoxyketones

DOI: 10.1016/S0040-4039(98)01856-5

Source and publish data:

Tetrahedron Letters p. 8277 - 8280 (1998)

Update date:2022-07-30

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Authors:

Hutin, Pierre

Petit, Yves

Larcheveque, Marc

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Article abstract of DOI:10.1016/S0040-4039(98)01856-5

The reductive amination of racemic 2,3-dialkoxyketones by tetrabutylammonium triacetoxyborohydride in the presence of (R) or (S)-α- methylbenzylamine allows the stereocontrolled access to 3-amino-1,2-diols in high enantiomerical purity via a partial dynamic resolution.

Full text of DOI:10.1016/S0040-4039(98)01856-5

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