Chemistry Letters p. 1177 - 1178 (1998)
Update date:2022-09-26
Topics:
Okuyama, Tadashi
Sato, Koichi
Ochiai, Masahito
Solvolysis of both E and Z isomers of a β,β-dialkylvinyl-(phenyl)iodonium salt gave extensively rearranged products. A mechanism involving a primary vinyl cation intermediate as well as the alkyl participation leading to secondary vinyl cations is proposed.
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