Aziridination of α,β-unsaturated ketones

DOI: 10.1016/S0040-4020(98)00870-9

Source and publish data:

Tetrahedron p. 14105 - 14112 (1998)

Update date:2022-07-30

Topics:

Authors:

Fioravanti, Stefania

Pellacani, Lucio

Tabanella, Stefania

Tardella, Paolo A.

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Article abstract of DOI:10.1016/S0040-4020(98)00870-9

α,β-Unsaturated ketones are aziridinated by [(arenesulphonyl)oxy]carbamates and CaO (or Cs₂CO₃) or by N₃CO₂Et photolysis. A remote chiral center induced up to 74% d.e. Bis-unsaturated substrates showed scarce re

Full text of DOI:10.1016/S0040-4020(98)00870-9

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