MECHANISTIC STUDIES OF THE PHOTODECOMPOSITION OF ARYLMETHYL SULFONES IN HOMOGENEOUS AND MICELLAR SOLUTIONS.

DOI: 10.1021/ja00318a038

Source and publish data:

Journal of the American Chemical Society p. 1789 - 1793 (1984)

Update date:2022-09-26

Topics:

Authors:

Gould Gould

Tung Tung

Turro Turro

Givens Givens

Matuszewski

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Article abstract of DOI:10.1021/ja00318a038

The mechanism of photodecomposition of aryl sulfones has been investigated by using both steady-state and time-resolved techniques. Direct evidence for radical and triplet-state intermediates is provided. A correlation is found between the dynamics of reaction of the intermediate triplet states with the stabilities of the intermediate radicals.

Full text of DOI:10.1021/ja00318a038

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